Methyl (2Z)-2-bromomethyl-3-(3-chlorophenyl)prop-2-enoate
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چکیده
منابع مشابه
Methyl (2Z)-2-bromomethyl-3-(3-chlorophenyl)prop-2-enoate
There are two independent mol-ecules (A and B) in the asymmetric unit of the title compound C11H10BrClO2, which represents the Z isomer. The methyl-acrylate moieties are essentially planar, within 0.084 (2) and 0.027 (5) Å in mol-ecules A and B, respectively. The benzene ring makes dihedral angles of 13.17 (7) and 27.89 (9)° with the methyl-acrylate moiety in mol-ecules A and B, respectively. T...
متن کاملMethyl (2Z)-2-bromomethyl-3-(2,4-dichlorophenyl)prop-2-enoate
In the title compound C11H9BrCl2O2, which represents the Z isomer, the methyl-acrylate moiety is essentially planar within 0.039 (2) Å and has an extended trans configuration. The benzene ring makes a dihedral angle of 28.3 (1)° with the mean plane of the methyl-acrylate moiety. The crystal packing is characterized by C-H⋯O hydrogen bonding and halogen-halogen inter-actions [Cl⋯Cl = 3.486 (3) Å...
متن کاملMethyl (2Z)-3-[(4-nitrophenyl)carbamoyl]prop-2-enoate
In the title compound, C(11)H(10)N(2)O(5), the amide group is nearly coplanar and the ester group approximately perpendicular to the vinyl C-HC=CH-C group [dihedral angles of 5.0 (2) and 88.89 (5)°, respectively]. This results in a short intra-molecular O =C⋯O=C contact of 2.7201 (17) Å between the amide O atom and the ester carbonyl C atom. The prop-2-enamide fragment and the nitro group make ...
متن کاملMethyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)methyl]-3-(4-methoxyphenyl)prop-2-enoate
In the title indole derivative, C22H21NO4, the dihedral angle between the benzene and pyrrole rings of indole moiety is 1.8 (1)°. The plane of the 4-meth-oxy-phenyl ring is oriented with a dihedral angle of 60.7 (1)° with respect to the plane of the indole moiety. The mol-ecular packing is stabilized by C-H⋯O hydrogen bonds which form a V-shaped chain arrangement along the bc plane of the unit ...
متن کاملEthyl (2Z)-3-hydroxy-3-(4-nitrophenyl)prop-2-enoate
The title compound, C11H11NO5, is essentially planar, with an r.m.s. deviation of 0.06 Å. The mol-ecular structure is stabilized by an intra-molecular O-H⋯O hydrogen bond. In the crystal, molecules are linked by two pairs of C-H⋯O hydrogen bonds, forming sheets, lying parallel to (101), which enclose R 4 (4)(26) ring motifs.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2013
ISSN: 1600-5368
DOI: 10.1107/s1600536813012117